Advances in Strained and Interesting Organic Molecules, by B. Halton PDF

By B. Halton

ISBN-10: 0080552234

ISBN-13: 9780080552231

ISBN-10: 0762306319

ISBN-13: 9780762306312

The 8th quantity of this sequence includes six chapters and describes numerous attention-grabbing strained and never so strained molecules and their use - or abuse - within the widest experience. This quantity encompasses a place precis of planar carbon networks, the sphere of strained allenesis addressed by way of contemplating the 5- to- nine-membered ring derivatives and this can be by way of an advent to the character of carbene geometry and using ESR spectroscopy in deducing carbene constitution. using strained molecules within the synthesis of significant new compounds of a common and non-natural nature is a prime topic within the quantity. different parts which are mentioned are strained carbohydrates, stereocontrolled entry to usual items and polymer structures in addition to a miles wanted contribution to the sequence on small-ring nitrogen heterocycles.

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Extra resources for Advances in Strained and Interesting Organic Molecules, Volume 8, Volume 8

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J. Org. , 64 (1999) 2947. , Ferrara, J. , and Youngs, W. , J. Chem. , Chem. , (1988) 548. [53] Ferrara, J. , and Youngs, W. , J. Am. Chem. , 107 (1985) 6719; Ferrara, J. , Tanaka, A. , and Youngs, W. , OrganometaUics, 8 (1989) 2089; Youngs, W. , Kinder, J. , Bradshaw, J. , and Tessier, C. , 12 (1993) 2406. [54] Ferrara, J. , and Youngs, W. , Organometallics, 6 (1987) 676; Ferrara, J. , and Youngs, W. , Inorg. , 27 (1988) 2201. [55] Ferrara, J. , and Youngs, W. , J. Am. Chem. , 110 (1988) 647.

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Iodination, desilylation, and intramolecular alkynylation with Pd(dba)2 under high dilution conditions furnished 72 as the sole product. Although this route required six more steps from commercially available materials, the overall yield was 35% as opposed to the reported 24% for Scheme 14. More importantly, larger cyclooligomeric macrocycles were not detected, facilitating product isolation and purification. The intramolecular cyclization strategy is indispensable for the construction of more complex substructures of the graphyne network, such as bis-macrocycle 84 (Scheme 16), which is otherwise impossible to synthesize by intermolecular routes [58].

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Advances in Strained and Interesting Organic Molecules, Volume 8, Volume 8 by B. Halton


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